Artykuły (WCh)

Stały URI dla kolekcjihttp://hdl.handle.net/11652/155

Przeglądaj

collection.search.results.head

Teraz wyświetlane 1 - 1 z 1
  • Pozycja
    Organocatalytic Enantioselective Approach to Spirocyclic Δβ,γ-Butenolides
    (2014) Hejmanowska, Joanna; Dzięgielewski, Marek; Kowalczyk, Dorota; Albrecht, Łukasz
    A novel method for the preparation of the spirocyclic Δβ,γ-butenolides is presented. The developed strategy is based on a trienamine-mediated [4+2]-cycloaddition between (E)-3-alkylidene- 5-arylfuran-2(3H)-ones and 2,4-dienals. Target products containing three contiguous centres including one quaternary are efficiently formed in a highly enantiomerically enriched form in the presence of the silyl-protected diphenylprolinol aminocatalyst.