Role of water in metal catalyst performance for ketone hydrogenation: a joint experimental and theoretical study on levulinic acid conversion into gamma-valerolactone
Brak miniatury
Data
2014
Tytuł czasopisma
ISSN czasopisma
Tytuł tomu
Wydawca
Abstrakt
While Ru is a poor hydrogenation catalyst compared to Pt or Pd in the gas phase, it is efficient under aqueous phase conditions in the hydrogenation of ketones such as the conversion of levulinic acid into gamma-valerolactone. Combining DFT calculations and experiments, we demonstrate that water is responsible for the enhanced reactivity of Ru under those conditions.
Opis
Słowa kluczowe
Cytowanie
Chemical Communications, Vol.50, Issue 83, pages 12450-12453