Carine, MichelJérémie, ZaffranRuppert, Agnieszka M.Matras-Michalska, JoannaJędrzejczyk, MarcinGrams, JacekSautet, Philippe2016-02-052016-02-052014Chemical Communications, Vol.50, Issue 83, pages 12450-12453http://hdl.handle.net/11652/1121http://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc04401k#!divAbstractWhile Ru is a poor hydrogenation catalyst compared to Pt or Pd in the gas phase, it is efficient under aqueous phase conditions in the hydrogenation of ketones such as the conversion of levulinic acid into gamma-valerolactone. Combining DFT calculations and experiments, we demonstrate that water is responsible for the enhanced reactivity of Ru under those conditions.enArtykuł