Browsing Wydział Chemiczny / Faculty of Chemistry / W3 by Author "Alaimo, Peter J."

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Cytochrome P450-catalyzed dealkylation of atrazine by Rhodococcus sp. strain NI86/21 involves hydrogen atom transfer rather than single electron transfer

Meyer, Armin H.; Dybała-Defratyka, Agnieszka; Alaimo, Peter J.; Geronimo, Inacrist; Sanchez, Ariana D.; Cramer, Christopher J.; Elsner, Martin (Royal Society of Chemistry, 2014)

Cytochrome P450 enzymes are responsible for a multitude of natural transformation reactions. For oxidative N-dealkylation, single electron (SET) and hydrogen atom abstraction (HAT) have been debated as underlying mechanisms. ...