Wydział Fizyki Technicznej, Informatyki i Matematyki Stosowanej / Faculty of Technical Physics, Information Technology and Applied Mathematics / W7

Stały URI zbioruhttp://hdl.handle.net/11652/7

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Adsorption induced hole transport in thin layers of non-ordered tetracene.
(Wydawnictwo Politechniki Łódzkiej, 2015) Kania, Sylwester; Kuliński, Janusz
Additional disorder induced by adsorption processes by the molecule of ambient are responsible for deep modulation of conductivity. Observations confirmed the dominated role of the increase of the free carrier concentration due to the increse the shallow trap concentration, for modulation of the conductivity.
Adsorption of ethanol to thin layer of acenes as a process of interconnected networks
(Wydawnictwo Politechniki Łódzkiej, 2013) Kania, Sylwester; Kuliński, Janusz
The activation process and the transport process for electrons in the tetracene layers and holes in the p-quaterphenyl layers is considered. Observed dependence of the conductivity on the vapor concentration of the activator molecules may suggests influence of collisions as a source of injection of charge through the surface potential barrier of adsorption. Applied model of two-body interactions in the interface of adsorption is approved on the basis of theory of area law for entanglement from exponential decay of correlations. Quantum description of adsorption of small hydrocarbon to the solid acenes involve only diagonal elements of the interaction matrix.
Correlated networks in the adsorptionenhanced currents
(Lodz University of Technology Press, 2014) Kania, Sylwester; Kuliński, Janusz
Injection of carriers into thin layers of acenes due to adsorption of ethanol activator molecules is considered as a electron transfer reaction between two phases. Complexity of the processes may be diminished with applying electron transfer theory in the meaning of Marcus.
Volume conductivity of polycrystalline tetracene and p-quaterphenyl layers modified under influence of the surface adsorption
(Wydawnictwo Politechniki Łódzkiej, 2021) Kania, Sylwester; Kuliński, Janusz; Kościelniak-Mucha, Barbara; Słoma, Piotr; Wojciechowski, Krzysztof
Volume conductivity of thin organic layers in contact with the ambient atmosphere depends on the volume properties and on the adsorption processes on the free surface of the layer. In order to clarify the role of the surface, experiments were carried out at a temperature close to 293 K to determine the influence of the adsorption dynamics on the change of characteristic relationships observed for the transport of electric charge in vacuum, in the ambient atmosphere and in the controlled atmosphere of the ethyl alcohol vapors. The investigations were carried out for two linear tetracyclic molecular structures, i.e. p-tetraphenyl and tetracene. These molecular systems differ in organization of the rings. The results show an increase in conductivity measured for both compounds when there are the molecules capable of adsorbing to the surface and to transfer or receive charge carriers connected with the process of diffusion or drift transport in the volume of the layer. The nature of the observed increase in conductivity proves that the hopping mechanism is present in the case of conductivity of both tested materials.